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Design, Synthesis and Characterization of new Supramolecular Architectures

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eBook details

  • Title: Design, Synthesis and Characterization of new Supramolecular Architectures
  • Author : Massimo Baroncini
  • Release Date : January 15, 2011
  • Genre: Chemistry,Books,Science & Nature,Professional & Technical,Engineering,
  • Pages : * pages
  • Size : 1793 KB

Description

This thesis focuses on the bottom-up design, construction and operation of supramolecular systems capable of behaving as devices and machines on the molecular scale, which is a topic of great interest in nanoscience and a fascinating challenge in nanotechnology. In particular, the systems investigated here include: polyviologen dendrimers capable of behaving as hosts and chargestoring devices; molecular machines based on pseudorotaxanes/rotaxanes and operated by photoinduced proton transfer, or photoisomerization reactions; and a simple unimolecular multiplexer/demultiplexer. The systems have been characterized using a variety of techniques including absorption and emission spectra, laser flash photolysis, NMR spectroscopy, electrochemical experiments, stopped flow measurements. This research addresses a large number of open problems in the nanosciences, dealing with a wide range of the most advanced applications of supramolecular systems.


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